标題: Gel polymer electrolytes for rechargeable batteries toward wide-temperature applications

作者: Zhou, XY (Zhou, Xiaoyan); Zhou, YF (Zhou, Yifang); Yu, L (Yu, Le); Qi, LH (Qi, Luhe); Oh, KS (Oh, Kyeong-Seok); Hu, P (Hu, Pei); Lee, SY (Lee, Sang-Young); Chen, CJ (Chen, Chaoji)

來源出版物: CHEMICAL SOCIETY REVIEWS DOI: 10.1039/d3cs00551h Early Access Date: APR 2024 Published Date: 2024 APR 18

摘要: Rechargeable batteries, typically represented by lithium-ion batteries, have taken a huge leap in energy density over the last two decades. However, they still face material/chemical challenges in ensuring safety and long service life at temperatures beyond the optimum range, primarily due to the chemical/electrochemical instabilities of conventional liquid electrolytes against aggressive electrode reactions and temperature variation. In this regard, a gel polymer electrolyte (GPE) with its liquid components immobilized and stabilized by a solid matrix, capable of retaining almost all the advantageous natures of the liquid electrolytes and circumventing the interfacial issues that exist in the all-solid-state electrolytes, is of great significance to realize rechargeable batteries with extended working temperature range. We begin this review with the main challenges faced in the development of GPEs, based on extensive literature research and our practical experience. Then, a significant section is dedicated to the requirements and design principles of GPEs for wide-temperature applications, with special attention paid to the feasibility, cost, and environmental impact. Next, the research progress of GPEs is thoroughly reviewed according to the strategies applied. In the end, we outline some prospects of GPEs related to innovations in material sciences, advanced characterizations, artificial intelligence, and environmental impact analysis, hoping to spark new research activities that ultimately bring us a step closer to realizing wide-temperature rechargeable batteries.

Design principles, engineering strategies, challenges, and opportunities of gel polymer electrolytes for rechargeable batteries toward wide-temperature applications are thoroughly reviewed.

地址: [Zhou, Xiaoyan; Zhou, Yifang; Yu, Le; Qi, Luhe; Chen, Chaoji] Wuhan Univ, Sch Resource & Environm Sci, Hubei Biomass Resource Chem & Environm Biotechnol, Wuhan 430079, Peoples R China.

[Zhou, Xiaoyan; Hu, Pei] Hubei Univ Technol, Sch Sci, Wuhan 430070, Peoples R China.

[Oh, Kyeong-Seok; Lee, Sang-Young] Yonsei Univ, Dept Chem & Biomol Engn, Seoul, South Korea.

通訊作者地址: Chen, CJ (通訊作者)，Wuhan Univ, Sch Resource & Environm Sci, Hubei Biomass Resource Chem & Environm Biotechnol, Wuhan 430079, Peoples R China.

Hu, P (通訊作者)，Hubei Univ Technol, Sch Sci, Wuhan 430070, Peoples R China.

Lee, SY (通訊作者)，Yonsei Univ, Dept Chem & Biomol Engn, Seoul, South Korea.

電子郵件地址: hupei@hbut.edu.cn; syleek@yonsei.ac.kr; chenchaojili@whu.edu.cn

影響因子：46.2