标題: An efficient Mn1-yCeyOx composite oxide mesoporous catalysts for catalytic combustion of aromatic hydrocarbon

作者: Guo, N (Guo, Na); Jiang, LX (Jiang, Luxiang); Wang, DT (Wang, Dengtai); Zhan, Y (Zhan, Yi); Wang, ZW (Wang, Zuwu)

來源出版物: ATMOSPHERIC POLLUTION RESEARCH 卷: 14 期: 4 文獻号: 101715 DOI: 10.1016/j.apr.2023.101715 出版年: APR 2023

摘要: A simple and effective method, pyrolytic melt polymerization using solid metal salts, was successfully synthesized catalysts with a mesoporous structure. A series of high-performance composite oxide catalysts made from the manganese oxide was prepared. The characteristics of these materials were evaluated using various technologies, such as XRD, BET, H2-TPR, and in-situ DRIFTS. The catalytic combustion performance of catalysts for typical aromatic hydrocarbon (toluene and CB) was investigated. And we speculated the catalytic reaction path of toluene by in-situ infrared analysis. Based on T90%, the catalytic activity ranking was: Mn0.8Ce0.2Ox>MnOx> Mn0.5Ce0.5Ox>Mn0.2Ce0.8Ox>CeOx. Furthermore, Mn0.8Ce0.2Ox exhibited excellent catalytic stability in the CB and toluene for 20 h. The increase of oxygen vacancies was attributed to the doping of Ce which increased the amount of Mn3+ and Ce3+. The active oxygen and abundant oxygen vacancies on the Mn0.8Ce0.2Ox promote the good catalytic performance for aromatic hydrocarbons.

作者關鍵詞: Molten polymerization; Catalytic combustion; Toluene; CB; Oxygen vacancies

地址: [Guo, Na; Jiang, Luxiang; Wang, Dengtai; Zhan, Yi; Wang, Zuwu] Wuhan Univ, Sch Resource & Environm Sci, Wuhan 430079, Peoples R China.

通訊作者地址: Wang, ZW (通訊作者)，Wuhan Univ, Sch Resource & Environm Sci, Wuhan 430079, Peoples R China.

電子郵件地址: hjgcapc@163.com

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