标題：CoO nanosheets in situ grown on nitrogen-doped activated carbon as an effective cathodic electrocatalyst for oxygen reduction reaction in microbial fuel cells作者：Huang, QS (Huang, Qiangsheng); Zhou, PJ (Zhou, Peijiang); Yang, H (Yang, Hua); Zhu, LL (Zhu, Longlong); Wu, HY (Wu, Huangying)

來源出版物： ELECTROCHIMICA ACTA卷：232頁碼：339-347 DOI：10.1016/j.electacta.2017.02.163 出版年：APR 1 2017

摘要：A low cost, naturally abundant, and highly active oxygen reduction reaction (ORR) electrocatalyst is essential for the commercialization of microbial fuel cells (MFCs). In this study, a promising strategy was proposed to prepare catalyst CoO nanosheets supported by nitrogendoped activated carbon (CoO@N-AC) to achieve a synergetic effect between metallic oxide and heteroatomdoped carbon. The nanocomposites possess a large Brunauer-Emmett-Teller surface area (1577.2 m(2) g (1)), low total resistance (9.26 Omega), and fourelectron ORR pathway. These nanocomposites are utilized as the aircathode catalysts in MFCs. CoO@N-AC remarkably increases the maximum power density by 122.5% from 741.5 +/- 8.5 mW m (2) to 1650.1 +/- 36.2 mW m +/- 2, which is higher than that of Pt/C (1201.4 +/- 13.5 mW m (2)). The excellent catalytic activity makes CoO@N-AC a promising cathodic electrocatalyst for practical application of MFCs.

入藏号： WOS:000398327300040

文獻類型：Article

語種：English

作者關鍵詞： CoO nanosheets; heteroatom; oxidation reduction reaction; activated carbon; microbial fuel cell

擴展關鍵詞： LITHIUM-ION BATTERIES; WASTE-WATER TREATMENT; AIR-CATHODE; COBALT OXIDE; EVOLUTION REACTIONS; ELECTRICITY-GENERATION; ASSISTED SYNTHESIS; ELECTRON-ACCEPTOR; POWER-GENERATION; CATALYST

通訊作者地址：Zhou, PJ (reprint author), Wuhan Univ, Sch Resource & Environm Sci, Hubei Biomass Resource Chem & Environm Biotechnol, Wuhan 430079, Peoples R China.

電子郵件地址：zhoupj@whu.edu.cn

地址： [Huang, Qiangsheng; Zhou, Peijiang; Yang, Hua; Zhu, Longlong; Wu, Huangying] Wuhan Univ, Sch Resource & Environm Sci, Hubei Biomass Resource Chem & Environm Biotechnol, Wuhan 430079, Peoples R China.

研究方向：Electrochemistry

ISSN：0013-4686

eISSN:1873-3859

影響因子：4.803