标題：Adsorption of tetracycline and sulfonamide antibiotics on amorphous nano-carbon作者：Yixiao Wu, Beidou Xi, Guangji Hu, Dihua Wang, Aimin Li, Weihao Zhang*, Lei Lu & Huijun Ding

來源出版物：Desalination and Water Treatment DOI：10.1080/19443994.2015.1135407 出版時間：13 Jan 2016

摘要：Antibiotics in the aquatic environment present potential risks to aquatic ecosystems. The adsorption of tetracycline (TC) and two sulfonamides (SAs), sulfadiazine (SD) and sulfamethoxazole (SMZ), from an aqueous solution of synthesized amorphous nano-carbon (ANC) was investigated. The ANC had a large adsorption capacity for TC (125.55 mg/g), SD (620.74 mg/g), and SMZ (332.21 mg/g). Several mechanisms (i.e. cation exchange, electrostatic interaction, hydrophobic effect, H-bonding, and π–π interactions) are potentially involved in the adsorption process. SAs were more strongly adsorbed on ANC because their molecules are smaller than those of TC. Adsorption nearly reached equilibrium within 2 h, with a removal rate of over 75%. Temperature and pH of the solution positively affected the adsorption process. Cations (Na+ and Ca2+) in solution had a slight effect on adsorption; Ca2+ inhibited adsorption, while Na+ promoted it. The adsorption process was fitted to pseudo-second-order kinetic and Freundlich models, which indicated that adsorption was both favorable and spontaneous. Fourier transform infrared spectroscopy revealed the interactions between antibiotics and ANC.

文獻類型：Article

語種：English

作者關鍵詞：Nanomaterials, Amorphous carbon, Tetracycline, Sulfonamide, Adsorption

通訊作者地址：Weihao Zhang, School of Resource and Environment Science, Wuhan University, Wuhan 430079, PR China

地址：

[Yixiao Wu, Dihua Wang,Weihao Zhang,Lei Lu & Huijun Ding]School of Resource and Environment Science, Wuhan University, Wuhan 430079, PR China.

[Beidou Xi]State Key Lab Environment Criteria & Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, PR China

[Guangji Hu]Environmental Engineering Program, University of Nortdhern British Columbia, Prince George, British Columbia V2N 4Z9, Canada

[Aimin Li]Hubei Environmental Monitoring Central Station, Wuhan 430072, PR China

[Weihao Zhang]Hubei Provincail Collaborative Innovation Center for Water Resources Security, Wuhan University, Wuhan 430072, PR China

ISSN：1944-3994

eISSN:1944-3986

影響因子（2014）：1.173

全文鍊接：http://www.tandfonline.com/doi/abs/10.1080/19443994.2015.1135407