标題：Interfacial Synthesis of Free-Standing Asymmetrical PPY-PEDOT Copolymer Film with 3D Network Structure for Supercapacitors

作者： Zhu, H (Zhu, Hua); Li, M (Li, Min); Wang, DH (Wang, Dihua); Zhou, SB (Zhou, Shoubin); Peng, C (Peng, Chuang)

來源出版物：JOURNAL OF THE ELECTROCHEMICAL SOCIETY 卷：164 期：9頁碼: A1820-A1825 DOI：10.1149/2.1401707jes 出版年： 2017

摘要：Advances in multi-electron transfer materials and architectured electrodes are two important strategies for innovations in electrochemical energy storage. We herein report the attainment of both by interfacial electrodeposition of freestanding PPY-PEDOT copolymer films. The composition of the copolymer is verified by FTIR and XPS spectra and the dispersion of PPY and PEDOT is studied by EDX mapping. SEM images show the film has an open porous 3D network microstructure. Electrochemical characterizations show that the copolymer film is an excellent supercapacitor electrode material with high specific capacitance, good power capability and cycle performance. The multi-electron transfer nature of the copolymer, the copolymerization synergistic effects and the unique microstructure are responsible for the improved charge-discharge performances.

入藏号：WOS:000413256400184

文獻類型：Article

語種：English

擴展關鍵詞： CONDUCTING POLYMERS; PYRROLE; 3,4-ETHYLENEDIOXYTHIOPHENE; ELECTROPOLYMERIZATION; ELECTRODE; POLYPYRROLE; COMPOSITE

通訊作者地址：Wang, DH; Peng, C (reprint author), Wuhan Univ, Hubei Int Sci & Technol Cooperat Base Sustainable, Sch Resource & Environm Sci, Wuhan 430072, Hubei, Peoples R China.

電子郵件地址：Wangdh@whu.edu.cn; Chuang.peng@whu.edu.cn

地址：[Zhu, Hua; Li, Min; Wang, Dihua; Peng, Chuang] Wuhan Univ, Hubei Int Sci & Technol Cooperat Base Sustainable, Sch Resource & Environm Sci, Wuhan 430072, Hubei, Peoples R China.

[Zhou, Shoubin] Huafu High Technol Energy Storage Co Ltd, Gaoyou High Tec Ind Pk, Yangzhou, Jiangsu, Peoples R China.

ISSN：0013-4651

eISSN: 1945-7111

影響因子：3.259