标題: Durability of platinum coating anode in molten carbonate electrolysis cell

作者: Du, KF (Du, Kaifa); Yu, R (Yu, Rui); Gao, MX (Gao, Muxing); Chen, ZG (Chen, Zhigang); Mao, XH (Mao, Xuhui); Zhu, H (Zhu, Hua); Wang, DH (Wang, Dihua)

來源出版物: CORROSION SCIENCE  卷: 153  頁: 12-18  DOI: 10.1016/j.corsci.2019.03.028  出版年: JUN 2019  

摘要: The performance and durability of a noble metal coating anode for oxygen evolution was investigated in molten Li2CO3-Na2CO3-K2CO3 at 450 degrees C for the first time. The consuming rate of Pt was evaluated to be below 4.1 x 10(-2) mm/a under anodic polarization by weight-loss and melt analysis measurements. The metallic substrate, titanium can be anodically passivated by forming a dense Li2TiO3 film in the melt. Platinum coated titanium (Pt/Ti) anode exhibited excellent durability within 100h electrolysis, but slight oxygen penetration under the coating was observed, which might lead to the failure of the material for much longer term application.

入藏号: WOS:000467669300002

語言: English

文獻類型: Article

作者關鍵詞: Platinum; Metal coatings; Molten salts; Polarization; Anodic dissolution; Oxidation

地址: [Du, Kaifa; Yu, Rui; Gao, Muxing; Chen, Zhigang; Mao, Xuhui; Zhu, Hua; Wang, Dihua] Wuhan Univ, Sch Resource & Environm Sci, Int Cooperat Base Sustainable Utilizat Resources, Wuhan 430072, Hubei, Peoples R China.

通訊作者地址: Wang, DH (通訊作者)，Wuhan Univ, Sch Resource & Environm Sci, Int Cooperat Base Sustainable Utilizat Resources, Wuhan 430072, Hubei, Peoples R China.

電子郵件地址: wangdh@whu.edu.cn

影響因子：4.862